Mineral oil hydrocarbons (MOSH/POSH and MOAH) - migration/extractable content
Analysis of migration of mineral oil hydrocarbons (MOH), including mineral oil saturated hydrocarbons (MOSH) with polyolefin oligomeric hydrocarbons (POSH) and mineral oil aromatic hydrocarbons (MOAH) from food contact materials (FCM) into a food simulant.
The results are reported as the concentrations of fractions of MOSH/POSH and MOAH, with grouping based on the number of carbon atoms in the substances. The reported fractions are listed in the table below:
MOSH/POSH (C10-C50), total | MOAH (C10-C50), total* |
|---|---|
MOSH/POSH (≥C10-≤C16) | MOAH (≥C10-≤C16) |
MOSH/POSH (>C16-≤C20) | MOAH (>C16-≤C25) |
MOSH/POSH (>C20-≤C25) | MOAH (>C25-≤C35) |
MOSH/POSH (>C25-≤C35) | MOAH (>C35-≤C50) |
MOSH/POSH (>C35-≤C40) | |
MOSH/POSH (>C40-≤C50) |
* Reporting of "MOAH (C10-C35), total" possible upon request (for evaluating paper/board for BfR XXXVI compliance)
The migration can be measured either via conventional migration or via aqueous/solvents extractions (in case of non-coated paper):
Migration method | Available simulants | Applicable standard | Typical reporting limit* |
|---|---|---|---|
Conventional migration | water, 3% acetic acid, 10%, 20%, 50%, and 95% ethanol, isooctane | EN 13130-1 | 5 µg/dm2 |
Conventional migration | olive oil | EN 13130-1 | 2 µg/dm2 |
Conventional migration | Tenax | EN 13130-1 EN 14338 | 5 µg/dm2 |
Aqueous extract | water | EN 645 EN 647 | 0.03 mg/l of extract |
Solvent extract | 95% ethanol, isooctane | EN 15519 | 0.03 mg/l of extract |
* Reporting limit can be higher in case of interference from the sample
POSH are not part of MOH but can be present in polyolefin plastics, such as polyethylene (PE) and polypropylene (PP). MOSH and POSH have very similar structures and they tend to elute together in chromatography. Thus in polyolefin plastics and materials with polyolefin layers, it is usually impossible to separate MOSH and POSH with normal analysis techniques.
The analysis includes a compliance assessment according to the following references:
MOSH fraction:
BfR documentation: Questions and answers on mineral oil components in food (31 July 2023)
MOAH fraction:
Standing Committee on Plants, Animals, Food and Feed Section Novel Food and Toxicological Safety of the Food Chain 19 October 2022
BfR recommendation XXXVI (as of 01.10.2025)
- Suitable sample matrices
- Food contact and packaging materials and articles
- Required sample quantity
- 2xA4-size sheets (migration); 30 grams (aqueous or solvent extractions)
- Typical turnaround time
- 4 weeks after receiving the samples
- Detection limit
- See description
- Available quality systems
- Accredited test method
- Device types
- Method expert
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