Polycyclic aromatic hydrocarbons (PAH) - REACH compliance

Phthalates are a group of chemicals widely used as plasticizers, which make plastics more flexible and durable. They have also been used as additives in products such as cosmetics and personal care items. Several phthalates have been identified as endocrine-disrupting agents or as chemicals toxic to reproduction. Exposure to phthalates can occur through: Oral exposure Food: Exposure occurs via migration from food packaging., Children's toys: Children often put toys in their mouths.., Inhalation: Breathing in dust from vinyl flooring or fragrances (like perfumes) can cause exposure to phthalates via inhalation., Skin contact: Phthalates present in cosmetics, lotions, and soaps can be absorbed through the skin.. For other listed matrices apart from cosmetics, the analysis package covers the following substances included in the REACH Authorization List: Substance Abbreviation CAS number Diisobutyl phthalate DIBP 84-69-5 Dibutyl phthalate DBP 84-74-2 Benzyl butyl phthalate BBP 85-68-7 Bis(2-ethylhexyl) phthalate DEHP 117-81-7 Di(n-octyl) phthalate DNOP 117-84-0 Diisononyl phthalate DINP 68515-48-0 Diisodecyl phthalate DIDP 26761-40-0 Products that contain restricted phthalates in concentrations higher than 0.1% may be removed from the market. The analysis package for cosmetic products contains the following phthalates: Substance Abbreviation CAS number Bis(2-ethylhexyl) phthalate DEHP 117-81-7 Benzyl butyl phthalate BBP 85-68-7 Dibutyl phthalate DBP 84-74-2 Diisononyl phthalate DINP 68515-48-0 Di(n-octyl) phthalate DNOP 117-84-0 Diisodecyl phthalate DIDP 26761-40-0 All the above-mentioned substances are prohibited in cosmetic products (Annex II of Regulation (EC) No 1223/2009).

Content of 15 polycyclic aromatic hydrocarbons (PAHs) in plastic and rubber and products made from them (e.g., toys, kitchenware) according to AfPS GS 2019:01 PAK. If PAH levels are sufficiently low, the product may be granted a GS mark (a voluntary German product safety label). The test package includes the following substances: Naphthalene [CAS: 91-20-3], Acenaphthylene [CAS: 208-96-8] , Acenaphthene [CAS: 83-32-9] , Fluorene [CAS: 86-73-7] , Phenanthrene [CAS: 85-01-8] , Anthracene [CAS: 120-12-7] , Fluoranthene [CAS: 206-44-0] , Pyrene [CAS: 129-00-0] , Benzo(a)anthracene [CAS: 56-55-3] , Chrysene [CAS: 218-01-9] , Benzo(b)fluoranthene [CAS: 205-99-2] , Benzo(k)fluoranthene [CAS: 207-08-9] , Benzo(j)fluoranthene [CAS: 205-82-3] , Benzo(e)pyrene [CAS: 192-97-2] , Benzo(a)pyrene [benzo(def)chrysene] [CAS: 50-32- 8] , Indeno(1,2,3-cd)pyrene [CAS: 193-39-5] , Dibenzo(a,h)anthracene [CAS: 53-70-3] , Benzo(g,h,i)perylene [CAS: 191-24-2].

We offer two extended analysis packages for phthalates and plasticizers in various matrices using the GC-MS technique. The first package covers 22 compounds with reporting limits significantly lower than the industry standard of 0.001%: Substance name Abbreviation CAS No Reporting limit (LOD) (wt%) Dimethyl phthalate DMP 131-11-3 0.00005 Diethyl phthalate DEP 84-66-2 0.00005 Triethyl citrate TEC 77-93-0 0.00025 Diallyl phthalate DAP 131-17-9 0.00005 Dipropyl phthalate DPrP 131-16-8 0.00005 Diisobutyl phthalate DIBP 84-69-5 0.00005 Dibutyl phthalate DBP 84-74-2 0.00005 Di-n-pentyl phthalate DPP 131-18-0 0.00005 Di-n-hexyl phthalate DHXP 84-75-3 0.00005 Dibutyl sebacate DBS 109-43-3 0.00005 Acetyl tributyl citrate ATBC 77-90-7 0.00005 Benzyl butyl phthalate BBP 85-68-7 0.00005 Diethylhexyl adipate DEHA 103-23-1 0.00005 Dicyclohexyl phthalate DCHP 84-61-7 0.00005 Di-2-ethylhexyl phthalate DEHP 117-81-7 0.00005 Di-n-octyl phthalate DNOP 117-84-0 0.00005 DINCH DINCH 166412-78-8 0.00005 Di-2-ethylhexyl sebacate - 122-62-3 0.00005 Dioctyl terephthalate DOTP 6422-86-2 0.00005 Diisononyl phthalate DINP 28553-12-0 0.00025 Diisodecyl phthalate DIDP 26761-40-0 0.00025 Phthalic anhydride - 85-44-9 0.00005 The other package covers 43 compounds with a detection limit of 0.001%. The full list of target substances is available upon request. Please let us know which option you are interested in when requesting a quote.

Targeted screening and quantification of PFAS compounds in various materials with accredited in-house LC-MS/MS methods. Number of substances covered by the method 77 substances analyzed, 126 substances listed (salts of analyzed acids, alcohols, etc.), Total of 203 substances reported, A list of substances is provided in a separate appendix together with the quotation. Examples of target analytes include PFOS, PFOA, PFHxS, and PFNA. The full list of compounds is available upon request. In addition to plastic and paper, the measurement is suitable for textiles, leather, wood, metals, paints, and coatings. One common application of this analysis is evaluating compliance with EU and US regulations on PFAS in food packaging. If this is the goal, a total (organic) fluorine (TOF) analysis should be conducted in addition to the targeted screening. We are happy to provide a single offer that includes both analyses.

Cyclosiloxanes are the primary building blocks of siloxane polymers and ultimately silicone rubber. Hence, cyclosiloxanes can remain in the final silicone article as residual impurities. Several cyclosiloxanes (D4, D5, D6) are considered harmful to the environment and human health. These three substances are listed in the REACH Candidate List of substances of very high concern (SVHC). The analysis package covers the following substances Substance CAS N:o Abbreviation Hexamethylcyclotrisiloxane 541-05-9 D3 Octamethylcyclotetrasiloxane 556-67-2 D4 Decamethylcyclopentasiloxane 541-02-6 D5 Dodecamethylcyclohexasiloxane 540-97-6 D6 Tetradecamethylcycloheptasiloxane 107-50-6 D7 Hexadecamethylcyclooctasiloxane 556-68-3 D8 The Nordic Swan Ecolabel criteria for greaseproof paper sets the limit values for D4, D5, and D6 impurities in silicone coating as 400 ppm per substance and 1000 ppm for the sum of D4, D5, and D6.

Analysis for quantifying dioxins and furans (PCDD/F) in various packaging materials (e.g. food and cosmetics packaging) and their raw materials, including plastics, paper, and rubber. Dioxins and furans are a family of chlorine-containing chemicals considered bioaccumulating, persistent organic pollutants (POPs) that can be toxic even at low doses. While regulatory limits apply mainly to food and feed, packaging materials can be a source of indirect exposure to dioxins and furans. Recycled materials tend to pose relatively high risks, depending on the quality of the raw material and the effectiveness of the decontamination process. The following substances are included in the analysis: Dibenzo-p-dioxins (PCDDs) Polychlorinated dibenzofurans (PCDFs) 2,3,7,8-TCDD. 2,3,7,8-TCDF. 1,2,3,7,8-PeCDD. 1,2,3,7,8-PeCDF. 1,2,3,4,7,8-HxCDD. 2,3,4,7,8-PeCDF. 1,2,3,6,7,8-HxCDD. 1,2,3,4,7,8-HxCDF. 1,2,3,7,8,9-HxCDD. 1,2,3,6,7,8-HxCDF. 1,2,3,4,6,7,8-HpCDD. 1,2,3,7,8,9-HxCDF. OCDD. 2,3,4,6,7,8-HxCDF. 1,2,3,4,6,7,8-HpCDF. 1,2,3,4,7,8,9-HpCDF. OCDF. Testing is often performed for the following reasons: Analyzing recycled PE, PP, and LDPE intended for cosmetics packaging according to CosPaTox guidelines., Analyzing paper and board bleached with elementary chlorine according to the requirements of TemaNord 2008:515 guidelines..

Determination of the total organic fluorine (TOF) content in combustible materials using combustion ion chromatography (CIC). By default, TOF is analyzed as total fluorine (TF). If required, total inorganic fluorine (TIF) can be measured as well, and TOF calculated as the difference between TF and TIF. TOF analysis gives information about the total amount of organic fluorinated compounds. It can also be used to evaluate the presence of per- and polyfluoroalkyl substances (PFAS) in the material, even though individual PFAS compounds can't be analyzed with this method. The analysis is suitable for many different materials. Please describe the sample in detail when requesting an offer to help us prepare a quote quickly.

Determination of mineral oil saturated hydrocarbons (MOSH) with polyolefin oligomeric saturated hydrocarbons (POSH) and mineral oil aromatic hydrocarbons (MOAH) in various matrices, including: Food contact materials (e.g., paper, board, plastics, rubber), Printing inks (incl. carbon black), Cosmetic products and raw materials, Lubricating oils and greases, white oils. The results are reported as the concentrations of fractions of MOSH/POSH and MOAH, with grouping based on the number of carbon atoms in the substances. The reported fractions are listed in the table below: MOSH/POSH (C10-C50), total MOAH (C10-C50), total MOSH/POSH (≥C10-≤C16) MOAH (≥C10-≤C16) MOSH/POSH (>C16-≤C20) MOAH (>C16-≤C25) MOSH/POSH (>C20-≤C25) MOAH (>C25-≤C35) MOSH/POSH (>C25-≤C35) MOAH (>C35-≤C50) MOSH/POSH (>C35-≤C40) MOSH/POSH (>C40-≤C50) In case the sample contains high amounts of MOSH, POSH, or poly alpha olefins (PAO), the levels should be indicated before shipping samples. Moreover, the LOQ is higher for samples with high MOSH, POSH, or PAO content due to dilution. Additionally, the safety data sheets (SDS) should be supplied with the samples when available.

Determination of the oxygen transmission rate of plastic films and sheet-like materials. The test is performed on two parallel samples simultaneously. Measurement conditions (temperature and relative humidity) can be chosen according to the intended use of the material. Oxygen permeability is typically measured at 23 °C and 0% relative humidity as per standard ASTM D3985. In moist conditions, for example at 38 °C and 90% relative humidity, standard ASTM F1927 is used. Please disclose the desired temperature (from 15 °C to 50 °C) and relative humidity (either 0% or 10% to 90%) upon requesting an offer. This measurement is suitable for materials with OTR values between 0.01 and 5000 cm3/(m2 * day).

Analysis package for silicone elastomers intended for food contact: Test parameter Limit Test method Regulatory reference Volatile content 0.5% Bestimmung von flüchtigen Verbindungen in Bedarfsgegenständen aus Silikon (version 02, 09/2023) BfR recommendation XV Residual peroxides Not detected 58. Mitteilung zur Untersuchung von Kunststoffen: Bundesgesundheitsblatt 40, (1997) BfR recommendation XV Release of odor and flavor No deterioration of organoleptic properties DIN 10955:2024 Regulation (EC) 1935/2004 Upon request, analysis of cyclosiloxanes can be included in the test package. Cyclosiloxanes are known impurities in silicone articles, and their concentrations must be very low for products to be eligible for sustainability labels, such as the Nordic Swan Ecolabel.